by Tiesheng Li  , Mingyu Wang  , Jie Liu  and Jinpeng Li

Received: 21 March 2022;  Published: 14 April 2022;  doi: 10.21926/cr.2202010

A new chiral cyclopalladated ferrocenyl imine catalyst (called 4a2) was designed and synthesized, and its self-assembly catalytic polymeric brush supported on silicon (denoted as Si@PB4a2) was also fabricated by surface-initiated atom transfer radical polymerization (ATRP) and characterized. The catalytic properties of monomer 4a2 in homogeneous and Si@PB4a2 in heterogeneous in Heck and Suzuki cross-coupling were investigated, respectively. They exhibited higher catalytic activity in Heck, and Suzuki coupling react [...]

by Anne Galarneau  , Lucie Desmurs  , Cyril Vaulot  , Habiba Nouali  , Benedicte Lebeau  , Jean Daou  , Vasile Hulea  , Claudia Cammarano  , Isabelle Batonneau-Gener  and Alexander Sachse

Received: 26 January 2022;  Published: 14 April 2022;  doi: 10.21926/cr.2202009

It is important to elucidate the role of the surface areas and pore volumes of hierarchical zeolites to understand their behavior as catalysts. Micro-and mesopore surface areas and volumes of the hierarchical MFI (Mobil Five zeolites) were assessed following several methods: (i) N2 adsorption at 77 K using classical and corrected t-plot analyses methods, (ii) pre-adsorption of n-nonane was followed by the study of the N2 adsorption at 77 K, and (iii) non-local-density functional theory (NLDFT) analysis using either [...]

by Rui Wang  , Dong Lin  , Minghuan Gao  , Linna Guo  , Tiesheng Li  and Minghua Liu

Received: 29 January 2022;  Published: 07 April 2022;  doi: 10.21926/cr.2202008

A series of novel Bi2MoO6/Ag/Ag2CrO4 heterostructure photocatalysts (denoted as BA-X, X = 1, 3, 5, 10) were synthesized using a coprecipitation method. These photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) and their photocatalytic properties were investigated. Compared with pure Bi2MoO6 or Ag2CrO4, BA-5 exhibited a higher photocatalytic property and broader light absorption. In addition, the surface pla [...]

by Thibaut Triquet  , Claire Tendero  , Laure Latapie  , Romain Richard  and Caroline Andriantsiferana

Received: 20 January 2022;  Published: 15 March 2022;  doi: 10.21926/cr.2201007

This work reports the performance of a sequential adsorption/photocatalysis process using activated carbon fibers with deposited TiO2 for the elimination of the antibiotic ciprofloxacin (CIP) in water. A commercial activated carbon fiber (ACF10) was selected as the support, and a TiO2 coating was synthesized using Metal Organic Chemical Vapor Deposition (MOCVD). Experiments were carried out using a photocatalytic reactor irradiated with monochromatic LEDs (365nm). Two different processes have been studied: adsorpti [...]

by Kate M. Waldie  and Sriram Katipamula

Received: 31 December 2021;  Published: 22 February 2022;  doi: 10.21926/cr.2201006

Fuel cells based on renewable synthetic fuels are promising alternatives to fossil fuel combustion for efficient electricity production. Much focus has been placed on hydrogen as a chemical fuel, but being a flammable gas, there are challenges with its safe handling. Formic acid is an attractive liquid fuel for use in direct formic acid or formate fuel cells, and it can in principle be produced from the thermal or electrochemical reduction of carbon dioxide. Over the past ten years, advances have been made in the d [...]

by José C. Conesa

Received: 29 November 2021;  Published: 21 February 2022;  doi: 10.21926/cr.2201005

It is important to understand the band offsets between semiconductors, which are crucial to determine the direction of electron transfer at the interfaces. Two methods are normally used to determine the direction from the first principles: alternating slabs put in contact (without empty spaces between them) and separate calculations for each material surface in the presence of vacuum spaces. The first method may introduce distortions due to insufficient epitaxial match, which may lead to bandgap changes, and the se [...]

by Xiu-Zhi Wei  , Jianguo Liu  and Longlong Ma

Received: 28 December 2021;  Published: 21 February 2022;  doi: 10.21926/cr.2201004

In recent years, research on converting biomass platform compounds into high-value chemicals and pharmaceutical intermediates has garnered huge interest. Nitrile and amide groups are key structures in natural products and biologically active molecules. The direct conversion of biomass platform compounds into nitriles and amides will undoubtedly be an important guide for biomass utilization. In this paper, a facile and efficient triphosgene-assisted one-pot conversion for aldehydes and ketones into nitrile and amide [...]

by Louguangshu Huang  , Hui Liu  , Xiaoxia Xue  , Wuduo Zhao  and Tiesheng Li

Received: 13 December 2021;  Published: 03 February 2022;  doi: 10.21926/cr.2201003

In this article, an approach to generate self-assembly cyclopalladated polythiophene imine monolayers (denoted as ITO@Pd-CPTIMs) is described. The monolayers were fabricated by combining self-assembly (SA), hybrid doping (HD), and electrochemical polymerization (ECP) called SA-HD-ECP. The catalytic activity and stability of the polymerized monolayers in the Suzuki coupling reaction were improved by modulating the structure and morphology in hybrid doping using different thiophene derivatives, concentrations, and sc [...]

by Jéssica A.P. Ponciano  and Marcelo S. Batista

Received: 01 December 2021;  Published: 26 January 2022;  doi: 10.21926/cr.2201002

In this paper, the relationship between activity and structure of Cu2+ in different chemical environments of Cu-BETA, La2CuO4, and CuO nanocatalysts was systematically investigated for acetonitrile combustion. The study revealed that exchanged and octahedral species of Cu2+ coexist in Cu-BETA, while octahedral species are dominant in CuO and La2CuO4. All nanocatalysts achieved high conversion rates of acetonitrile, which rapidly increased with temperature. CuO and La2CuO4 led to the formation of undesired products [...]

by Fabien Drault  , Youssef Snoussi  , Camila P. Palombo Ferraz  , Joelle Thuriot-Roukos  , Svetlana Heyte  , Ivaldo Itabaiana Junior  , Maya Marinova  , Sebastien Paul  and Robert Wojcieszak

Received: 25 October 2021;  Published: 13 January 2022;  doi: 10.21926/cr.2201001

Regardless of their size, supported gold nanoparticles are largely used for liquid-phase oxidation reactions. Small gold nanoparticles exhibit good performance during the reduction of organic compounds. The direct reduction of carboxylic acid to aldehyde is a famous and familiar reaction in the field of organic chemistry and is considered as one of the fundamental chemical transformations. Herein, we present Au/hydrotalcite, Au/MgO, and Au/Al2O3 systems as heterogeneous versatile catalysts to realize the oxidation [...]