Dearomatization of the Kerosene Fraction: Kinetic Studies


Abstract
(ISSN 2771-490X)
Catalysis Research is an international peer-reviewed Open Access journal published quarterly online by LIDSEN Publishing Inc. This periodical is devoted to publishing high-quality papers that describe the most significant and cutting-edge research in all areas of catalysts and catalyzed reactions. Its aim is to provide timely, authoritative introductions to current thinking, developments and research in carefully selected topics.
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It publishes a variety of article types: original research, review, communication, opinion, study protocol, comment, conference report, technical note, book review, etc.
There is no restriction on paper length, provided that the text is concise and comprehensive. Authors should present their results in as much detail as possible, as reviewers are encouraged to emphasize scientific rigor and reproducibility.
Dearomatization of the Kerosene Fraction: Kinetic Studiesby
![]() ![]() Abstract The kinetics of dearomatization of a kerosene fraction processed using a zeolite catalyst (0.9 HZSM-5) at different temperatures (160-200°C), the molar ratio between the aromatic hydrocarbons present in the kerosene fraction and n-decene (1:(0.5-4)), and the reaction time (1-3 h) were studied. Based on the obtained data, a kinetic model for kerosene [...] |
3D Fe3O4-decorated Nitrogen-doped Graphene Aerogel as a Highly Durable Electrocatalyst for Oxygen Reduction ReactionsAbstract The rational design of efficient electrocatalysts for oxygen reduction reaction (ORR) is the key to developing fuel cells and metal-air batteries. Carbon-supported iron-based materials, as the most promising electrocatalysts for ORR, have drawn much attention as they are cost-effective and exhibit high activity. In this work, a three-dimensional (3D [...] |
Synthesis of a Solid Base Catalyst Formed from Zinc(II) Acetylacetonate and Consisting of MgO Modified with ZnOAbstract Solid base catalysts consisting of MgO modified with 10 mol% ZnO (ZnO/MgO) were prepared by depositing zinc(II) acetylacetonate (Zn(acac)2) in polar and nonpolar organic solvents on the surface of MgO and Mg(OH)2. The process was followed by thermal decomposition in air at 773 K over a period of 3 h. The activity of MgO modified with Zn(acac)2 for base [...] |
Visible-Light-Induced Formation of Aromatic Ketones: A Metal-Free C−H Oxygenation Process in Air under Room TemperatureAbstract The process of light-induced C-H oxygenation is of high interest as it can be used for the construction of oxygenated compounds. Herein, we report a mild and general method for the efficient synthesis of aromatic ketones following the process of metal-free C-H oxygenation. With air as the oxidant, high functional tolerance was demonstrated, and the [...] |
Lipases: Sources of Acquisition, Ways of Production, and Recent Applicationsby
![]() ![]() ![]() Abstract Enzymes are extensively used in biotechnological processes in several areas of industry. They are sustainable and safe, and their specificity is another characteristic that improves the performance in the process. Among enzymes, lipase is relevant due to the ability to play different roles in the industry and the possibility of collecting them from [...] |
Recent Advances in the Application of Perovskite Catalysts in the Dry Reforming of MethaneAbstract The use of the dry reforming of methane (DRM) to convert the two principal greenhouse gases, methane and carbon dioxide, to syngas (a mixture of H2 and CO) has attracted increasing attention in recent years. However, the DRM reaction suffers from the twin disadvantages of carbon deposition and sintering, so a highly efficient and robust catalyst with [...] |
Pd-Cu Bimetallic Based Catalysts for Nitrate Remediation in Water: Synthesis, Characterization, and the Influence of Supportsby
![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() Abstract The use of Pd-Cu bimetallic catalysts in the reduction of aqueous nitrate ions by hydrogen was studied. The catalysts were supported on multi-walled carbon nanotubes (MWCNTs), activated carbon (AC), and Titania, and the influence of the support on the nitrate reduction activity in water was then investigated. The catalysts were characterized before [...] |
A New Chiral Cyclopalladated Ferrocenylimine Self-assembly Polymeric Film supported on Silicon for Heck and Suzuki-coupling ReactionsAbstract A new chiral cyclopalladated ferrocenyl imine catalyst (called 4a2) was designed and synthesized, and its self-assembly catalytic polymeric brush supported on silicon (denoted as Si@PB4a2) was also fabricated by surface-initiated atom transfer radical polymerization (ATRP) and characterized. The catalytic properties of monomer 4a2 in homogeneous and [...] |
Hierarchical MFI Zeolite Catalysts: How to Determine Their Textural Properties?-A Comparative Studyby
![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() Abstract It is important to elucidate the role of the surface areas and pore volumes of hierarchical zeolites to understand their behavior as catalysts. Micro-and mesopore surface areas and volumes of the hierarchical MFI (Mobil Five zeolites) were assessed following several methods: (i) N2 adsorption at 77 K using classical and corrected t-plot analyses methods [...] |
Preparation of a Novel Bi2MoO6/Ag/Ag2CrO4 Catalyst with Promoted Visible Light Photodegradation of RhB DyeAbstract A series of novel Bi2MoO6/Ag/Ag2CrO4 heterostructure photocatalysts (denoted as BA-X, X = 1, 3, 5, 10) were synthesized using a coprecipitation method. These photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) and their photocatalytic properties [...] |
The Use of Composite TiO2/Activated Carbon Fibers as a Photocatalyst in a Sequential Adsorption/Photocatalysis Process for the Elimination of CiprofloxacinAbstract This work reports the performance of a sequential adsorption/photocatalysis process using activated carbon fibers with deposited TiO2 for the elimination of the antibiotic ciprofloxacin (CIP) in water. A commercial activated carbon fiber (ACF10) was selected as the support, and a TiO2 coating was synthesized using Metal Organic Chemical Vapor Deposition [...] |
Recent Progress in the Development of Molecular Electrocatalysts for Formate Oxidationby
![]() ![]() Abstract Fuel cells based on renewable synthetic fuels are promising alternatives to fossil fuel combustion for efficient electricity production. Much focus has been placed on hydrogen as a chemical fuel, but being a flammable gas, there are challenges with its safe handling. Formic acid is an attractive liquid fuel for use in direct formic acid or formate fuel [...] |
Determining the Band Alignment at the BiVO4|NiOOH Interface Using the Hybrid DFT TechniqueAbstract It is important to understand the band offsets between semiconductors, which are crucial to determine the direction of electron transfer at the interfaces. Two methods are normally used to determine the direction from the first principles: alternating slabs put in contact (without empty spaces between them) and separate calculations for each material [...] |
One-Pot Tandem Synthesis of Nitriles and Amides from Biomass Platform CompoundsAbstract In recent years, research on converting biomass platform compounds into high-value chemicals and pharmaceutical intermediates has garnered huge interest. Nitrile and amide groups are key structures in natural products and biologically active molecules. The direct conversion of biomass platform compounds into nitriles and amides will undoubtedly be an [...] |
Controllable Cyclopalladated Polythiophene Imine Monolayer by Self-Assembly, Hybrid Doping and Electrochemical Polymerization: A Simple Way to Enhance Activity and StabilityAbstract In this article, an approach to generate self-assembly cyclopalladated polythiophene imine monolayers (denoted as ITO@Pd-CPTIMs) is described. The monolayers were fabricated by combining self-assembly (SA), hybrid doping (HD), and electrochemical polymerization (ECP) called SA-HD-ECP. The catalytic activity and stability of the polymerized monolayers [...] |
Acetonitrile Combustion over Copper-Based Nanocatalysts: A Structure-Performance Relationship Studyby
![]() ![]() Abstract In this paper, the relationship between activity and structure of Cu2+ in different chemical environments of Cu-BETA, La2CuO4, and CuO nanocatalysts was systematically investigated for acetonitrile combustion. The study revealed that exchanged and octahedral species of Cu2+ coexist in Cu-BETA, while octahedral species are dominant in CuO and La2CuO4 [...] |
Versatility of Supported Gold Nanoparticles on Hydrotalcites used for Oxidation and Reduction Reactionsby
![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() ![]() Abstract Regardless of their size, supported gold nanoparticles are largely used for liquid-phase oxidation reactions. Small gold nanoparticles exhibit good performance during the reduction of organic compounds. The direct reduction of carboxylic acid to aldehyde is a famous and familiar reaction in the field of organic chemistry and is considered as one of [...] |
Effect of Acid Treatment on the Properties of Zeolite Catalyst for Straight-Run Gasoline UpgradingAbstract The objective of this research was to analyze the effect of different concentrations of nitric and hydrochloric acids on the structural, acidic, and catalytic properties of a post-synthetic treated ZSM-5 type zeolite at various temperatures. The properties of zeolite catalysts were determined using different methods, such as the Brunauer-Emmett-Teller [...] |
Stability of a Fe-Rich Cathode Catalyst in an Anion Exchange Membrane Fuel Cellby
![]() ![]() Abstract Fe-rich alloys have been widely studied as catalyst materials for the cathodic oxygen reduction reaction (ORR) in hydrogen fuel cells, and many have shown high activities. The stability of Fe-rich catalysts has also been researched, and some studies have shown promising results using an accelerated stress test (AST), which uses a potential cycling metho [...] |
Photocatalytic Degradation of Azo Dyes Using Microreactors: Mechanistic Study of its Effects on H2O2 AdditionAbstract The photocatalytic reaction involved in TiO2 photocatalysis was investigated using a microreactor coated with TiO2 film on the glass plate attached on one side of the microreactor. It was confirmed that the effect of H2O2 on the photocatalytic degradation efficiency of azo dyes (acid orange 7, acid red 151, and acid yellow 23) was dependent on the pol [...] |
Development of an Efficient Bi-Functional Catalyst made of a Novel Hybrid Material for Rechargeable Zn-Air BatteryAbstract One-pot synthesis of mesoporous hybrid material consisting of Mn-Co/CoO nanoparticles encapsulated in an N-doped graphene shell decorated with Mo2C nanoparticles (Mo2C-NC@Mn-Co/CoO) was reported. The Mn and Mo components synergistically refined the graphitized carbons due to the interactions with N and C atoms while promoting the stability of the Co [...] |
Catalysis Research Welcomes New Editorial Board Member
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We welcome Prof. Michael Harmata from University of Missouri-Columbia, USA, to join the Editorial Board of Catalysis Research. Prof. Harmata is a Norman Rabjohn Distinguished Professor of Chemistry, Department of Chemistry, University of Missouri-Columbia, Columbia, USA. Prof. Harmata has extensive experience in synthetic and medicinal organic chemistry, organic chemistry, and catalysis. We are grateful to Prof. Harmata for his participation and support.
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We welcome Prof. Ajay K Ray from Western University, Canada, to join the Editorial Board of Catalysis Research. Prof. Ray is a Professor from Department of Chemical and Biochemical Engineering, Western University, London, ON N6A 5B9, Canada. Prof. Ray has extensive experience in industrial process modeling and optimization, development of solar photocatalysis, and advancement of simulated moving bed technology for reactive separation. We are grateful to Prof. Ray for his participation and support.
Catalysis Research Welcomes New Editorial Board Member
We welcome Dr. Maria H. L. Ribeiro from University of Lisbon, Portugal, to join the Editorial Board of Catalysis Research. Dr. Ribeiro is an Associate Professor, Faculty of Pharmacy, University of Lisbon, 1649-003 Lisbon, Portugal. Dr. Ribeiro has extensive experience in biocatalysis, enzyme immobilization, stabilization and purification, bioactive compounds, microreactors, bioprocesses optimization, and pharmaceutical biotechnology. We are grateful to Dr. Ribeiro for her participation and support.
By 2030, the bio-based economy is expected to have grown significantly in Europe. One of the pillars of this bioeconomy is the concept of BIOREFINERY, the sustainable processing of several kinds of waste and biomass into a spectrum of marketable products and energy. While in the past many research efforts have been conducted towards understanding, modelling and designing conversion processes that can sustain a true circular economy, this KNOWLEDGE IS QUITE FRAGMENTED and UNEVENLY DISTRIBUTED across Europe. Several countries lack proper policies and public engagement to address the challenges ahead. HARMONIZATION must start on ROBUST KNOWLEDGE, and the ability to cover the WHOLE VALUE-CHAIN, from source materials up to the marketable products… and that is WIRE’s mission.
The WIRE COST Action broadly organizes into 4 KEY WORKING GROUPS (WG) that bring together experts from ACADEMIA, INDUSTRY and TECHNOLOGY TRANSFER organizations:
WG 1: Raw Materials
WG 2: Biorefinery Conversion Technologies
WG 3: Biorefinery Applications
WG 4: Communication and Dissemination.
These WG will proactively contribute to:
For more details, please visit: http://wire-cost-eu.ipportalegre.pt/
Topic: Sustainability in a Changing World
The event is the biannual national meeting of the American Chemical Society (ACS). It aims to give chemistry professionals an opportunity to share ideas and advance scientific and technical knowledge. It will attract thousands of chemical professionals and provide participents with opportunities for sharing their passion for chemistry, connecting with the scientific society, and advancing their career.
The theme "Sustainability in a Changing World" will be at the core of programming.
For more details, please visit: https://www.acs.org/content/acs/en/meetings/acs-meetings.html
Topic: Bonding Through Chemistry
Biannual national meeting of the American Chemical Society (ACS) covering the complete field of chemistry
Gives scientific professionals a platform to present, publish, discuss, and exhibit the most exciting research discoveries and technologies in chemistry and its related disciplines. The meeting will facilitate networking opportunities, career development and placement, and provide companies an opportunity to exhibit products and services to a targeted audience.
For more details, please visit: https://www.acs.org/content/acs/en/meetings/acs-meetings.html
Catalysis Research welcomes the following types of articles: original research, review, communication, opinion, case report, comment, conference report, technical note, book review, etc. There is no restriction on the length of the papers, color figures, supplementary file types. More details please see Instructions for Authors.
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