Homogeneous {Ti2Ni} Heterotrinuclear Catalyst for Ethylene Polymerization and Copolymerization
Abstract
(ISSN 2771-490X)
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Hetero-/Homo-geneous Catalysis in Organic Synthesis and Sustainable Chemistry
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Guest Editors
Amoolya Dattatraya Lalsare, PhD
Process Engineer at Intel Corporation Inc., West Virginia University, Morgantown, WV 26506, USA
Research Interests: Heterogeneous catalysis; Natural gas and biomass conversion to syngas; Syngas to chemicals
Luísa Margarida Martins, PhD
Associate Professor, Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal
Research Interests: Functionalized materials (in particular, involving C-scorpionates); Catalysis (homogeneous, supported or nano- catalysis); Electrochemistry
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Publication
Homogeneous {Ti2Ni} Heterotrinuclear Catalyst for Ethylene Polymerization and Copolymerizationby
Luiz Felipe da M. Rocha
,
Leonardo C. Ferreira
,
Maria de Fatima V. Marques
,
Rodrigo S. Bitzer
and
Marco Antônio Chaer Nascimento
Abstract We synthesized and spectroscopically characterized a new heterotrimetallic {Ti2Ni} ethylene (co)polymerization precatalyst containing one (α-diimine)NiBr2 and two (phenoxy-imine)TiCl4 scaffolds. Its calculated structure was investigated at the DFT B3LYP/LACVP** level. Our [...] |
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