Research Requirements to Move the Bar forward Using Aqueous Formate Salts as H2 Carriers for Energy Storage Applications
Abstract
1453 8358
Research Requirements to Move the Bar forward Using Aqueous Formate Salts as H2 Carriers for Energy Storage Applicationsby
Katarzyna Grubel
,
Ji Su
,
Jotheeswari Kothandaraman
,
Kriston Brooks
,
Gabor A. Somorjai
and
Tom Autrey
Abstract
In this perspective on hydrogen carriers, we focus on the needs for the development of robust active catalysts for the release of H2 from aqueous formate solutions, which are non-flammable, non-toxic, thermally stable, and readily available at large scales at reasonable cost. Formate salts can be stockpiled in the solid state or dissolved in water for long term storage and transport using existing infrastructure. Furthermore, formate salts are readily regenerated at moderate pressures using the same catalyst as for [...] 1453 8358 |
Testing the Correlation between Prior Knowledge of - and Visualisation Guided WTPs for Reducing the Visual Impacts Visual from Offshore Wind FarmsAbstract
Visual external costs are significant elements in the cost-benefit analysis of wind farm locations. This has been demonstrated well in the literature. However, in the assessment of the visual costs, a large share of the earlier studies used no or only simplistic visualizations of the visual impacts at stake. The cost estimates thus rely on the respondents’ ability to imagine the visual impacts associated with wind turbines of different sizes and at different locations. This has been argued to potentially reduce the [...] 1507 6887 |
Grid Integration of a Residential PV-based Hybrid Renewable Energy System Using High-Frequency Multi-winding TransformerAbstract
In this paper, a topology of a residential hybrid renewable energy system based on a high-frequency multi-winding transformer is introduced and analyzed. The system includes a PV and a wind-turbine as renewable energy sources, a battery as energy storage and their energies are integrated through a high-frequency transformer. In fact, the transformer integrates the energies in a magnetic form and also isolates the system inputs and outputs. The integrated output from renewables and battery is a DC high-voltage and i [...] 1466 8302 |
Sustainability Implications of Using Hydrogen as an Automotive Fuel in Western AustraliaAbstract
Hydrogen is regarded as a potential solution to address future energy demands and environmental protection challenges. This study assesses the triple bottom line (TBL) sustainability performance of hydrogen as an automotive fuel for Western Australia (WA) using a life cycle approach. Hydrogen is considered to be produced through water electrolysis. Two scenarios, current grid electricity and future renewable-based hydrogen, were compared with gasoline as a base case. The results show that locally produced grid elec [...] 1487 9045 |
Seismic Imaging of Convective Geothermal Flow Systems to Increase Well ProductivityAbstract
A core feature of convective geothermal resource production is wellbore energy flow Q ~ ρC x T x V. E.g., for wellbore fluid of volume heat capacity ρC ~ 4.3MJ/m3∙oC, temperature T ~ 230oC, and volumetric flow V ~ 50L/s, wellbore heat energy production is Q~ 50MWth ~ 5MWe. Wellbore fluid flow V =2πr0φv0ℓ for open wellbore length ℓ is given in turn by the spatially variable product crustal porosity times crustal fluid velocity v ≡ φv0 at the wellbore radius r0. For a geothermal wellbore to be productive (nominal Q ~ [...] 1420 9731 |
A Simplified Optimization Model for Sizing Proton-Exchange Membrane Fuel CellsAbstract
The fluctuations in the cost of energy coupled with the gradual decrease in natural resources (i.e., oil, natural gas, coal) and the environmental issues caused by the extensive use of fossil fuels, demand the urgent need for the development of advanced and clean energy systems. The European Union has requested new measures to target climate and energy deterioration by developing renewable energy sources by 2030. The stochastic character of the energy sources and the fluctuation in demand for the energy systems pos [...] 1451 8308 |
Computational Micromechanics for the Optimization of Compression Strength of Unidirectional Carbon Fiber Composites for Use in Wind Turbine Bladesby
Ryan J. Clarke
and
David A. Miller
Abstract
As wind turbine blades grow longer, new design parameters gain additional importance such as blade weight, tip deflection and material cost. These parameters require designers to relook at carbon fiber as a potential design solution. However, the composite materials in wind turbine blades are subjected to significant compressive loading, and the compressive strength of carbon fiber reinforced polymer (CFRP) composites is much lower than its tensile strength. This reduction in compression strength is due to a change [...] 1240 7104 |
Using Additives to Control the Decomposition Temperature of Sodium BorohydrideAbstract
Hydrogen (H2) shows great promise as zero-carbon emission fuel, but there are several challenges to overcome in regards to storage and transportation to make it a more universal energy solution. Gaseous hydrogen requires high pressures and large volume tanks while storage of liquid hydrogen requires cryogenic temperatures; neither option is ideal due to cost and the hazards involved. Storage in the solid state presents an attractive alternative, and can meet the U.S. Department of Energy (DOE) constraints to find m [...] 2170 12007 |
The Impact of Operating Conditions on the Performance of a CH4 Dry Reforming Membrane Reactor for H2 ProductionAbstract
Biogas is a promising resource for the production of H2 since it liberates energy by recycling waste, along with the reduction of CO2. In this paper, the biogas dry reforming membrane reactor is proposed to produce H2 for use in fuel cells. Pd/Cu alloy membrane is used to enhance the performance of the biogas dry reforming reactor. This study aims at understanding the effect of operating parameters such as feed ratio of sweep gas, pressure in the reactor, and reaction temperature on the performance of the biogas dr [...] 1313 8167 |
Hierarchically-Structured Ti/TiO2 Electrode for Hydrogen Evolution Synthesized via 3D Printing and AnodizationAbstract
Hierarchically-structured, electro-catalysts consisting of a titanium core with controlled macro-porosity and a thin titania surface-layer with controlled nano-porosity were synthesized via combination of additive manufacturing and in-situ anodization. The electrodes were tested for hydrogen evolution reaction and depicted competitive electro-catalytic activities, with Tafel slopes between 40 and 56 mV dec-1. The electrodes also depicted competitive onset and over potentials when compared with other electrode alter [...] 1344 9478 |
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